PARTITIONING OF SOME HEAVY METALS IN SELECTED DUMPSITE SOILS USING CHEMICAL SPECIATION TECHNIQUE

Files

PARTITIONING OF SOME HEAVY METALS.pdf (782.71 KB)

Date

2008-05-11

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Department of chemistry nasarawa state university keffi

Abstract

partitioning of some particulate trace metal Cd,Cr,cU,nI,pB AND zn in the siol of three dumsite (amudipe,A Yeyemi and Odopegtu site) in akure city of undo state, nigeria was caried out by selective sequential extraction procedues. other soil physico-cehemical parameters that influence the mobility and bioavailability of metal in soil were also determine. the soils, which were lsand-loamy, had soil reaction within the neutral and slightly alkaline pH range of 7.15 +-0 to 7.2+- with moderately high total organic matter content of 3.40+-0..26 6.64-0.51%. the percentage total metal distribution irMhe various rhpmirnt<fa°'^rll-lC™at!erc,ontentof3‘tO±0.26 6.64±0.51%. Thepercentagi (100%) > 0 (96.07%) > Pb(84 65%) > tbreedumPsi‘e and were Amudipe dumpsite, Cu Zn(81.73%) > Cr(57.57%) > Ph75Q %£?-839$ >™(*™7%). Ayeyemi dumpsite, Cd(96.40%) > Cu(86.40%o > Zn(74.93%) > Ni(63 20%) > CrUS d7°/\ a"d °doPetu dumpsite Cd(100%) > Carb. E. Red and 0,£altogether colllZT %), Pb(2f63%)- However, the non-residual fractions (Exch.. mplicatinghigh anthropogenic contribution to th^Tals'ToZenL^nsl

Description

Aticle

Keywords

Chemical speciation, heavy metals, dumpsite soil.

Citation

Aiyesanmi, A.F. 2005. Assessment of heavy contamination of Rodertkiri oil Field's soil. Nig. J. Soil Science, Vol. 15; 42- 46 Baranowski R., Rybak, A.; Baranowska 2002. Speciation Analysis of Elements in soil samples by XRF. Polish J. Environ.Sstudies, 11(5): 473-482. Bermond A., Yousfi I.; Ghestem ____ approach to the chemical speciation of trace metals in soils. Analyst, 123:785 - 789. Gale, N.L., Adams, C. D., Wixson, B.G., Loftin, K.A.. Huang, Y. 2002. Lead concentrations in fish and river sediments in the Old Lead Belt of Missouri; Environ. Sci. Technol. 36:4262-4268. metal Gale, N.L., Adams, C.D., Wixson, B.G., Loftin, K.A.; Huang, Y. 2004. Lead, zinc, copper and cadmium in fish and sediments from the Rig River and Flat River Creek of Missouri's Old Lead Belt; Environ. Geochem. Health, 26:37 49. P 1998. Kinetic Gruebel, K.A., Davis, J.A.; Lockie., J.O. 1988. The feasibility of using sequential extraction techniques for arsenic and selenium in soils and sediments. Soil Sci. Soc. Am. J. 52:390 - 397. Calmano, W., Mangold, S.; Welter, E.,(2001. An XAFS investigation of the artifacts caused by sequential extraction analyses of pb-contaminated FreseniusJ. Anal. Chem. 371: 823 - 830. soils. Chem. B.,ShemX.,ShenD.; Mon S. Gruter,U.M., Kresimon J.; Himer A.V. 2000. A new HG/LT-GC/ICP-MS multielement speciation technique for real samples in different matrices. FresemiusJ. Anal. Chem 368:67 - 75 1997. Nature of the Hcl-soluble sulfate in the sequential extraction for surphur speciation in soils. Fresenius J. Anal. Chem. 357:941 -949. D’Amore J. J., Al-Abed S. R. Scheckel, K.G;Ryan J.A. 2005. Methody for speciation of metals in soil: A Review .J. Environ. Qual. 34:170 Hendershot, W.H.; Lalande, H.; Duquette, M. 1993. Soil reaction and exchangeable Acidity. In Soil sampling and Methods of Analysis, (Ed.Carter, M.R.), Canadian Society of Soil Science, Lewis Publishers, London; pp 141-145. Holm P.F., Andersen S.; Christensen T.H., 1995. Speciation of dissolved Cd: interpretation of dialysis, ion exchange and computer (GEOCHEM) methods. Water Res. 29(3): 803-820. -175. Davidson Ch. M., Ferreira P.S.C.; URE, A.M. 1999. Some sources of variability in application of three-stage sequential extraction procedures recommended by BCR to industrially contaminated soil. Fresenius J. Anal. Chem. 363:746-760. DPR 2002. Environmental Guidelines and Standards for the Petroleum Industry in Nigeria (Revised edition), Departmemt of Petroleum Resources, Ministry of Petroleum and Mineral Resources. saure, M.P., Mauceau, A., Geoffroy, N., Laboudique, A., Tamura, N.; Marcus, M.A. 2005. Zinc mobility and speciation in soil covered by contaminated dredged sediment using micrometer-scale and bulk averaging X-ray fluorescence, absorption and diffraction techniques. Geochim, Cosmochim Acta 69:1173 1198. Karczewska A. 1996 Metal Species distribution in top and sub soil Appl. Geochem. 11:35-43. Egila .J.N. and Nimyeh A.D.N 2002. “Determination of trace metal speciation in sediment from some dams” J. Chem. Soc. Nig. 27 (1): 71 74. FAO 1990. Guideline for Soil Description 3rd Edition (Review). Soil Resources Management and conservation services. Land and Water Development Division FAO Rome. 102

URI

https://keffi.nsuk.edu.ng/handle/20.500.14448/5473

Collections

Articles