Aqua regia and ethylenediaminetetracetic acid (EDTA) trace metal levels in agricultural soil

dc.contributor.authorTukura, Bitrus Wokhe
dc.contributor.authorUsman, N.L.
dc.contributor.authorMohammed, H.B.
dc.date.accessioned2023-12-14T06:53:46Z
dc.date.available2023-12-14T06:53:46Z
dc.date.issued2013-09-24
dc.description.abstractSoil samples were collected from irrigation farmlands along the bank of Mada River and analysed for aqua regia and ethylenediaminetetracetic acid (EDTA) extractable trace metal (Cd, Cr, Cu, Pb, Zn Ni, Fe and Mn) concentrations. Water samples at source were also collected for analysis. Metal levels were quantified using atomic absorption spectrometry (AAS). Aqua regia and EDTA extractable Fe and Cd concentrations were the highest and lowest, respectively. The highest and lowest aqua regia and EDTA trace metal concentrations were recorded at sites 1 and 3, respectively. Aqua regia trace metal levels were generally higher than that of EDTA, but below the critical values for irrigation soil. Soils were extremely enriched with Cd (153 – 289), and deficient in Fe (0.5 – 1.0) contents. Fe Kd was generally the highest (21.45 – 44.35 kgl-1) and Zn (0.03 – 0.08 kgl-1) the lowest. Higher total metal contents result in a lower proportion of metal being sorbed, because potential absorption sites are filled in decreasing order of affinity. Strong and positive correlations existed for Cr/Zn (0.9879) and Cu/Ni (0.8077) at Site 1, Cu/Ni (0.9229) and Pb/Pb 0.9581) at Site 2, and Ni with Cr (0.9440) and Cu (0.8153) at Site 3. Significant correlations for soil-water indicated contributions of irrigation water to total metal contents in soil.en_US
dc.identifier.citationAdefila EO, Onwordi CT, Ogunwande IA (2010). Level of heavy metals uptake on vegetables planted on poultry droppings dumpsite. Arch. Appl. Sci. Res. 2(1):347-353. Akan JC, Abdulrahman F, Sodipo OA, Ochanya AE, Askira YK (2010). Heavy metals in sediments from River Ngada,Maiduguri Metropolis, Borno State, Nigeria. J. Environ. Chem. Ecotoxicol. 2(9):131-140. Akpoveta OV, Osakwe SA, Okoh BE, Otuya BO (2010). Physicochemical characteristics and levels of some heavy metals in soils around metal scrap dumps in some parts of Delta State, Nigeria. J. Appl. Sci. Environ. Manage. 14(4):57-60.en_US
dc.identifier.urihttps://keffi.nsuk.edu.ng/handle/20.500.14448/5502
dc.language.isoenen_US
dc.publisherDepartment of Chemistry, Faculty Of Natural And Applied Sciences, Nasarawa State University, Keffien_US
dc.subjectTrace metal, soil, aqua regia, ethylenediaminetetracetic acid (EDTA), enrichment factor, partition coefficient.en_US
dc.titleAqua regia and ethylenediaminetetracetic acid (EDTA) trace metal levels in agricultural soilen_US
dc.typeArticleen_US

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