KINETICS AND ISOTHERM STUDIES FOR ADSORPTION OF METHYL RED ONTO COMMERCIAL ACTIVATED CARBON

dc.contributor.authorL. G, Hassan.
dc.contributor.authorB. N, Ajana
dc.contributor.authorK. J, Umar.
dc.contributor.authorD. M, Sahabi.
dc.contributor.authorA. U., Itodos.
dc.contributor.authorA., Uba.
dc.date.accessioned2023-12-14T06:53:59Z
dc.date.available2023-12-14T06:53:59Z
dc.date.issued2011-11-10
dc.description.abstractBatch equilibrium and kinetics studies were carried out to study the rate and mechanism of dye uptake by commercial activated carbon. The percentage attrition (hardness),Bulk Density, Ash Content and methylene blue (mesoporosity) test were investigated. Comparison of the best fit model was made by evaluating the goodness of fit using the correlation coefficient values. (R2), sum of squares error (SSE) and the standard error (SE) of the estimate, which follow the trend, langmuir (R2=0.959, SSE=3.889, SE=3.118)>Freundlich (R2=0.901, SSE-9.449, SE=4.860). The smaller the values of SSE and SE, he better the curve fitting. Langmuir model gave the best curve fitting with smaller values of SSE and SE. The maximum theoretical adsorption capacity (q„J of the activated carbon was also evaluated using the Langmuir model the and the q^ was found to be 64.10 which shows that the activated carbon has a good adsorption capacity. The Elcmic and Intraparticle diffusion kinetic models were both applied to the adsorption kinetic data obtained. The Elovic equation gave the best fit with correlation coefficient of (0.995) and Intraparticle diffusion model (0.951).en_US
dc.identifier.citationAbdul, A.; Aberuagba, F. 2005. Comparative study of the Adsorption of the Phosphate by activated carbon from corncobs, Groundnut shell and Rice-husk. A.U.J. T., 9(1): 59 - 63. Ahmedna, M.; Marsha, W.; Rao, M. 2000. Production of Granular activated carbon from selected Agric by products. Bioresources and Technolog 71(2): 113 -123. Bansode, R.; Losso, J.; Marshall, E.; Rao, M.; Portier, J. 2003. Adsorption of volatile organic compound by Pelen and almond Shell based activated carbon. Bioresource Technology, 90(2): 175 -184. Brunner, W.; Focht, D. D. 1973. Deterministic threehalf order kinetic model for microbial degradation of added carbon substrates in soil. Appl. Enxhron. Microbial, 47:1211 -1216. 613. Omomnhenle, S.; Ofomaja, A.; Okieimen, F. 2006. Sorption of methylene blue by unmodified and modified citric acid sawdust. Journal Chemical Society ofNigeria, 30(1,2): 161 -164. Sabio, E.; Gonzalez, E.; Gonalek, J. F.; Gonzalez Garcia, G M.; Ramiro, A.; Ganan, J. 2004. "Thermal regeneration of activated carbon exhausted with p-nitrophenol". Carbon, 42(11): 2285 -2293. Srivastara, V. G; Mall, I. D.; Mistra, I. M. 1989. Characterization of mesoporous rice husk ash (RHA) and adsorption kinetic of metal ions from aqueous solution onto RHA. Journal of Hazardous Materials, B134:257- 267. jy •c Quen, S. H.; Clayton, W. R. 1980. Application of Toles, C. A.; Marshall, W. E.; John Wartelle, L. H; Mcaloon, A. 2000. Add activated carbon from Almond shell. Bioresource Tech., 71:87-97. U.S. Environmental Protection Agency. 1973. Process design manual for carbon adsorption. U.S.E.P.A. National environmental Research center, Cincinnati, OH. Weber, W. J.; Morris, J. C. 1963. Kinetics of adsorption on carbon from J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89:31 -60. Elovich equation to the kinetic of phosphate release and sorption on soils. Sci, Soc. Am. J., 44: 265-268. Emmanuel, K. A.; Romaraju, K. A.; Somasekhara Rao, K. 2007. Removal of Mn (II) from aqueous solutions using Bombax mamabanum fruit she substrate. Elec. J. Chem., 4(3): 419 - 427. Giles, C. H.; Smith, D.; Huitson, A. 1974. "A general treatment and classification of the solute isotherm. I: TNadeem, M.; Mahmood, A.; Shahid, S. A.; Shah, S. S.; Khalid, A. M.; Mckay, G. 2006. Sorption of lead from aqueous solution by chemically modified carbon adsorbent. J. Hazard Mater, 138(3): 604-613en_US
dc.identifier.urihttps://keffi.nsuk.edu.ng/handle/20.500.14448/5523
dc.language.isoenen_US
dc.publisherDepartment of Chemistry, Nasarawa State University Keffien_US
dc.subjectCommercial activated carbon, isotherms, kinetics, methyl red, methylene blue, adsorption.en_US
dc.titleKINETICS AND ISOTHERM STUDIES FOR ADSORPTION OF METHYL RED ONTO COMMERCIAL ACTIVATED CARBONen_US
dc.typeArticleen_US

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